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Now showing items 11-20 of 39
Conversion of F-BODIPYs to Cl-BODIPYs: Enhancing the Reactivity of F-BODIPYs
(2013-01)
A new method for the synthesis of Cl-BODIPYs from F-BODIPYs is reported, merely requiring
treatment of the F-BODIPY with boron trichloride. Cl-BODIPYs are exploited as synthetic
intermediates generated in situ for the ...
Investigations into the nucleophilic meso-substitution of F-BODIPYs and improvements to the synthesis of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene.
(2011)
A series of three F-BODIPYs, with varying levels of steric crowding about the meso-position were
selected to investigate nucleophilic meso-substitution of F-BODIPYs. The synthesis of one of these
F-BODIPYs, 4,4-difluor ...
The first series of alkali dipyrrinato complexes
(2010-08)
The first series of alkali dipyrrinato complexes is reported, encompassing lithium, sodium, and
potassium salts of meso-unsubstituted and meso-aryl-substituted derivatives. By varying the
substituents at the meso position, ...
Thionation Reactions of 2-Pyrrole Carboxylates
(RSC, 2016)
Prodigiosenes Conjugated to Tamoxifen and Estradiol
(Royal Society of Chemistry, 2017)
Decarboxylative Arylation of Substituted Pyrroles N-protected with 2-(Trimethylsilyl) ethoxymethyl (SEM)
(Canadian Journal of Chemistry, 2018)
Palladium-catalyzed decarboxylative arylation is reported using pyrroles N-protected with the 2-(trimethylsilyl) ethoxymethyl (SEM) group and featuring 2-, 3- and 4-substituents about the pyrrolic framework. In contrast ...
Synthesis and biological evaluation of prodigiosene conjugates of porphyrin, estrone and 4-hydroxytamoxifen
(Bioorganic & Medicinal Chemistry, 2013)
To generate the first series of prodigiosene conjugates, the tripyrrolic skeleton was appended to estrone, tamoxifen and porphyrin frameworks by way of ester linkers and various hydrocarbon chain lengths. The ability of ...
An Improved Method for the Synthesis of F-BODIPYs from Dipyrrins and Bis(dipyrrin)s
(Organic Letters, 2012)
An improved methodology for the synthesis of F-BODIPYs from dipyrrins and bis(dipyrrin)s is reported. This strategy employs lithium salts of dipyrrins as intermediates that are then treated with only one equivalent of boron ...
Celebrating the 200th anniversary of Dalhousie University in Halifax, Nova Scotia, Canada.
(Canadian Journal of Chemistry, 2018)