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Step-wise synthetic approach is necessary to access g-conjugates of folate: folate-conjugated prodigiosenes
(2019)
Despite the vast literature that describes reacting folic acid with a pharmacophore, this route is ineffective in providing the correct regioisomer of the resulting conjugate. We herein present a step-wise route to the ...
Classifying donor strengths of dipyrrinato/aza-dipyrrinato ligands
(2019)
A parameter is reported by which to use 13C NMR chemical shifts to measure and predict the donor capabilities of N^N dipyrrinato and aza-dipyrrinato ligands chelating in L^X fashion. The results enable the rationalisation ...
The Photodecarboxylation of Substituted Naphthylmethyl Arylacetate Esters: Synthesis of Naphthylarylethanes
(2019)
The synthesis of naphthylarylethanes via the photodecarboxylation of naphthylmethyl arylacetate
esters is reported where the aryl group is able to stabilize a charge transfer reaction. The reaction
proceeds via intramolecular ...
Synthesis and reactivity of 2-thionoester pyrroles: a route to 2-formyl pyrroles
(RSC Advances, 2019)
2-Functionalised pyrroles exhibit considerable synthetic utility. Herein, the synthesis and reactivity of 2-thionoester (-C(S)OR) pyrroles is reported. 2-Thionoester pyrroles were synthesized using a Knorr-type approach ...
Bridging and Conformational Control of Porphyrin Units through Non-Traditional Rigid Scaffolds
(Wiley, 2019-11)
Connecting two porphyrin units in a rigid linear fashion,
without any undesired electron delocalization or communication
between the chromophores, remains a synthetic challenge. Herein, a
broad library of functionally ...
Bridging and Conformational Control of Porphyrin Units through Non-Traditional Rigid Scaffolds
(2019-11-07)
Connecting two porphyrin units in a rigid linear
fashion, without any undesired electron delocalization or
communication between the chromophores, remains a synthetic
challenge. Herein, a broad library of functionally ...