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A study of phase transitions in cadmium perchlorate hexahydrate (Cd(ClO4)2.6H2O) by adiabatic calorimetry and infrared spectroscopy.
(1985)
A calorimetric study of Cd(ClO4)2.6H2O from 20 to 345 K shows 3 phase transformations, at 124.8,
238.45, and 271.62 K. IR spectra indicate that the low-temp. structure (below 124.8 K) contains 1
type of [Cd(OH2)6]2+, of ...
Phase transitions in metal perchlorate hydrates: the supposed hydrate-to-pseudohydrate transformations.
(1984)
A polemic. The hydrate-to-pseudohydrate transformations in metal perchlorate hydrates reported
by M. B. Patel and H. D. Brist (ibid. 1983, 79, 4489) and Solid State Commun. (48, 139 (1983)) as
well as the suggested ...
Phase transitions in M(ClO4)2.6H2O (M = magnesium, zinc). Investigations by adiabatic calorimetry and infrared spectroscopy.
(1986)
IR spectra of Mg(ClO4)2.6H2O at 10 K indicate a complex structure contg. at least 16 distinct
types of H2O protons. At 107.9 K this structure transforms sharply to a much simpler disordered form
(?Strans = 7.754 J K-1 ...