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Facile Deprotection of F-BODIPYs using Methylboronic Acid
(2020)
4,4-Difluoro-4-bora-3a,4a-diaza-s-indacenes (F-BODIPYs) are deprotected through removal of
the –BF2 moiety upon treatment with methylboronic acid. The tolerance of various substitution
patterns about the dipyrrinato core ...
Bis[Pyrrolyl Ru(II)] Triads: a New Class of Photosensitizers for Metal-Organic Photodynamic Therapy
(2020)
A new family of ten dinuclear Ru(II) complexes based on the bis[pyrrolyl Ru(II)] triad scaffold,
where two Ru(bpy)2 centers are separated by a variety of organic linkers, was prepared to evaluate
the influence of the ...
Synthesis, properties and reactivity of BCl2 aza-BODIPY complexes and salts of the aza-dipyrrinato scaffold
(Royal Society of Chemistry, 2020-02-25)
The synthesis and characterisation of the BCl2-chelated complexes of both archetypal aza-dipyrrin sub- types are presented. A stepwise halogen exchange, leading to a mixed-halide Cl–B–F intermediate, is implicated in the ...