Browsing Chemistry Faculty Research, Publications and Presentations by Title
Now showing items 1-20 of 235
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Activation and Deprotection of F-BODIPYs using Boron Trihalides
The activation of F-BODIPYs with boron trihalides, followed by treatment with a nuclephile, effects facile substitution at boron; using water as the nucleophile promotes deprotective removal of the–BF2 moiety and thereby ... -
All-Dry Synthesis of Single Crystal NMC Cathode Materials for Li-Ion Batteries
Single crystal (SC) cathode materials with a layered structure are considered to be state-of-the-art for lithium ion batteries. However, their production involves many steps and can produce large amounts of wastewater. ... -
Amorphous carbon nanowires investigated by near-edge-x-ray-absorption-fine-structures
No abstract available. -
Antimicrobial Activity of Non-natural Prodigiosenes
Tripyrrolic prodigiosenes, derivatives of the natural product prodigiosin, have been produced via multi-step synthesis beginning with 2-formyl pyrroles bearing various functionalities at the 4-position. Two tin complexes ... -
Apparatus for dynamical thermal measurements of low-thermal diffusivity particulate materials at subambient temperatures
Apparatus for measurement of thermal diffusivity of particulate matter in the temperature range of 10-300 K is described. The basis of the measurement is modulated radial heat flow into a cylindrical sample, with a relatively ... -
Asymmetric oxidation of 2-(arylsulfenyl)pyrroles
The asymmetric oxidation of prochiral 2-(arylsulfenyl)pyrroles has been investigated. A marked electronic effect within the substrate significantly influenced the degree of enantioselectivity obtained, with very high enantio ... -
Automated SDS depletion for mass spectrometry of intact membrane proteins through transmembrane electrophoresis
Membrane proteins are underrepresented in proteome analysis platforms because of their hydrophobic character, contributing to decreased solubility. Sodium dodecyl sulfate is a favored denaturant in proteomic workflows, ... -
Automated, low-temperature dielectric relaxation apparatus for measurement of air-sensitive, corrosive, hygroscopic, powdered samples
An automated apparatus for dielectric determinations on solid samples was designed to allow cryogenic measurements on air-sensitive, corrosive, hygroscopic, powdered samples, without determination of sample thickness, ... -
Automated, small sample-size adiabatic calorimeter.
An automated adiabatic calorimeter is described with an internal vol. of 5 cm3, operable at 30-380 K. One of the main advantages of this calorimeter over others in use is the shorter down time during sample changes, due ... -
Bis[Pyrrolyl Ru(II)] Triads: a New Class of Photosensitizers for Metal-Organic Photodynamic Therapy
A new family of ten dinuclear Ru(II) complexes based on the bis[pyrrolyl Ru(II)] triad scaffold, where two Ru(bpy)2 centers are separated by a variety of organic linkers, was prepared to evaluate the influence of the ... -
BODIPYs with Chalcogenophenes at Boron: Synthesis and Properties. Postprint
Reported herein are the synthesis and characterization of BODIPYs bearing heterocycles at boron. To synthesize this series, various chalcogenophenes (furan, thiophene, selenophene, and tellurophene) were lithiated and then ... -
Bridging and Conformational Control of Porphyrin Units through Non-Traditional Rigid Scaffolds
Connecting two porphyrin units in a rigid linear fashion, without any undesired electron delocalization or communication between the chromophores, remains a synthetic challenge. Herein, a broad library of functionally ... -
Bridging and Conformational Control of Porphyrin Units through Non-Traditional Rigid Scaffolds
Connecting two porphyrin units in a rigid linear fashion, without any undesired electron delocalization or communication between the chromophores, remains a synthetic challenge. Herein, a broad library of functionally ...