Synthesis and Properties of Tetra-aryl Azobispyrroles
| dc.contributor.author | Steve O. Sequeira | |
| dc.contributor.author | Roberto M. Diaz-Rodriguez | |
| dc.contributor.author | Mmasinachi Atansi | |
| dc.contributor.author | James W. Hilborn | |
| dc.contributor.author | Adil Alkaş | |
| dc.contributor.author | Rosinah Liandrah Gapare | |
| dc.contributor.author | Madeleine Dearden | |
| dc.contributor.author | Em C. Sullivan | |
| dc.contributor.author | Emily B. Brown | |
| dc.contributor.author | Katherine N. Robertson | |
| dc.contributor.author | Alison Thompson | |
| dc.date.accessioned | 2025-07-29T18:21:18Z | |
| dc.date.available | 2025-07-29T18:21:18Z | |
| dc.date.issued | 2025 | |
| dc.description.abstract | An unprecedented azobispyrrole framework is introduced, wherein two aryl-substituted pyrroles are joined by an azo (–N[double bond, length as m-dash]N–) linkage. Functionalisation was demonstrated via pyrrolic N-methylation and by –BF2 complexation using the coordinating abilities of the pyrrolic and azo nitrogen atoms. Control of co-planarity enables tunability with maximal absorption and emission spanning almost 300 nm. | |
| dc.identifier.citation | Alkaş, Adil & Diaz-Rodriguez, Roberto & Sequeira, Steve & Hilborn, James & Atansi, Mmasinachi & Sullivan, Em & Brown, Emily & Gapare, Rosinah & Mutus, Bulent & Robertson, Katherine & Thompson, Alison. (2025). Introducing the substituted azobispyrrole framework: synthesis and properties. Chemical communications (Cambridge, England). 10.1039/d5cc02884a. | |
| dc.identifier.uri | https://hdl.handle.net/10222/85249 | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.ispartof | Chemical Communications | |
| dc.title | Synthesis and Properties of Tetra-aryl Azobispyrroles |