Introducing the Substituted Azobispyrrole Framework: Synthesis and Properties
| dc.contributor.author | Alkaş, Adil | |
| dc.contributor.author | Diaz-Rodriguez, Roberto M. | |
| dc.contributor.author | Sequeira, Steve O. | |
| dc.contributor.author | Hilborn, James W. | |
| dc.contributor.author | Atansi, Mmasinachi | |
| dc.contributor.author | Sullivan, Em C. | |
| dc.contributor.author | Brown, Emily B. | |
| dc.contributor.author | Gapare, Rosinah Liandrah | |
| dc.contributor.author | Mutus, Bulent | |
| dc.contributor.author | Robertson, Katherine N. | |
| dc.contributor.author | Thompson, Alison | |
| dc.date.accessioned | 2025-07-28T17:44:12Z | |
| dc.date.available | 2025-07-28T17:44:12Z | |
| dc.date.issued | 2025-07-03 | |
| dc.description.abstract | An unprecedented azobispyrrole framework is introduced, wherein two aryl-substituted pyrroles are joined by an azo (-NN-) linkage. Functionalisation was demonstrated via pyrrolic N-methylation and by -BF2 complexation using the coordinating abilities of the pyrrolic and azo nitrogen atoms. Control of co-planarity enables tunability with maximal absorption and emission spanning almost 300 nm. | |
| dc.identifier.citation | Alkaş A, Diaz-Rodriguez RM, Sequeira SO, Hilborn JW, Atansi M, Sullivan EC, Brown EB, Gapare RL, Mutus B, Robertson KN, Thompson A. Introducing the substituted azobispyrrole framework: synthesis and properties. Chem Commun (Camb). 2025 Jul 3. doi: 10.1039/d5cc02884a. Epub ahead of print. PMID: 40605751. | |
| dc.identifier.uri | https://hdl.handle.net/10222/85243 | |
| dc.relation.ispartof | Chemical Communications | |
| dc.title | Introducing the Substituted Azobispyrrole Framework: Synthesis and Properties | |
| dc.type | Article |