Asymmetric oxidation of 2-(arylsulfenyl)pyrroles

dc.contributor.author	Thompson, Alison	en_US
dc.contributor.author	Garabatos-Perera, Jose R.	en_US
dc.contributor.author	Gillis, H. Martin	en_US
dc.date.accessioned	2013-08-12T17:55:03Z
dc.date.available	2013-08-12T17:55:03Z
dc.date.issued	2008-07	en_US
dc.description.abstract	The asymmetric oxidation of prochiral 2-(arylsulfenyl)pyrroles has been investigated. A marked electronic effect within the substrate significantly influenced the degree of enantioselectivity obtained, with very high enantio selectivity being obtained for 5-(nitrobenzensulfenyl)pyrrole-2-carboxaldehydes using Ti(i-PrO)(4)/(+)-(R,R)-DET/H(2)O/CHP. This result bodes well for optimizing the asymmetric oxidation of other diaryl sulfides, substrates that have previously given only low enantiomeric excesses.	en_US
dc.identifier.citation	Thompson, Alison, Jose R. Garabatos-Perera, and H. Martin Gillis. 2008. "Asymmetric oxidation of 2-(arylsulfenyl)pyrroles." Canadian Journal of Chemistry-Revue Canadienne De Chimie 86(7): 676-681.	en_US
dc.identifier.issn	0008-4042	en_US
dc.identifier.issue	7	en_US
dc.identifier.startpage	676	en_US
dc.identifier.uri	http://dx.doi.org/10.1139/V08-054	en_US
dc.identifier.uri	http://hdl.handle.net/10222/30742
dc.identifier.volume	86	en_US
dc.relation.ispartof	Canadian Journal of Chemistry-Revue Canadienne De Chimie	en_US
dc.title	Asymmetric oxidation of 2-(arylsulfenyl)pyrroles	en_US
dc.type	article	en_US

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