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Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)

Date

2012-08

Authors

Lundrigan, Travis
Jackson, Carla L. M.
Uddin, Md Imam
Tucker, Lloyd A.
Ali, Adeeb Al-Sheikh
Linden, Anthony
Cameron, T. Stanley
Thompson, Alison

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Abstract

The synthesis and characterization of the first heteroleptic pyrrolide/2,2'-bipyridyl complexes of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react with Ru(bipy)(2)Cl-2.2H(2)O to form complexes in which the pyrrolide ligands chelate to Ru(II). The library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl derivatives.

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Citation

Lundrigan, Travis, Carla L. M. Jackson, Md Imam Uddin, Lloyd A. Tucker, et al. 2012. "Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)." Canadian Journal of Chemistry-Revue Canadienne De Chimie 90(8): 693-700.

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