Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)
Date
2012-08
Authors
Lundrigan, Travis
Jackson, Carla L. M.
Uddin, Md Imam
Tucker, Lloyd A.
Ali, Adeeb Al-Sheikh
Linden, Anthony
Cameron, T. Stanley
Thompson, Alison
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Abstract
The synthesis and characterization of the first heteroleptic pyrrolide/2,2'-bipyridyl complexes
of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react
with Ru(bipy)(2)Cl-2.2H(2)O to form complexes in which the pyrrolide ligands chelate to Ru(II). The
library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl
derivatives.
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Citation
Lundrigan, Travis, Carla L. M. Jackson, Md Imam Uddin, Lloyd A. Tucker, et al. 2012. "Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)." Canadian Journal of Chemistry-Revue Canadienne De Chimie 90(8): 693-700.