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Disiloxanes and other artifacts from a reversed-phase high pressure liquid chromatography identified by mass spectrometry

Date

1987-12

Authors

Russell, D.W.
Gillis, H.A.

Journal Title

Journal ISSN

Volume Title

Publisher

Dalhousie Printing Centre

Abstract

When a mixture of hydrophobic compounds was separated by reversed-phase high-performance liquid chromatography, one product was heavily contaminated with a mixture of long-chain alkyldisloxanes. These compounds, together with silanols, silyl ethers, and poly(dimethylsiloxanes), were formed by hydrolysis of the bonded phase.
Quand un mélange de composés hydrophobiques a été séparé par la chromatographie liquide à haute performance en phase inverse un des produits a été fortement contaminé par un mélange des disiloxanes alkyles à chaînes longues. Ces composés, ainsi que les silanols, les ethères silylés, et les poly(diméthylesiloxanes), ont été formés par l’hydrolyse de la phase stationnaire.

Description

Includes b&w ill., b&w charts, bibliographic references

Keywords

Biochemistry, Mass spectrometry, Chromatography, Nova Scotia

Citation

Russell, D.W., Gillis, H.A. (1986). Disiloxanes and other artifacts from a reversed-phase high pressure liquid chromatography identified by mass spectrometry. Proceedings of the Nova Scotian Institute of Science, 37(1), 13-19.