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The Suzuki–Miyaura Reaction of BPin-substituted F-BODIPYs with Aryl Halides

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2021-01-12

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Abstract

F-BODIPYs substituted with BPin functionality have been coupled to aryl halides using a mild and efficient catalyst system involving Pd2(dba)3 and XPhos. The methodology enables the Suzuki–Miyaura cross-coupling of electron-rich, electron-poor, and sterically encumbered BPin-substituted F-BODIPYs to aryl halides bearing various functional groups, thus presenting an opportunity for the preparation of highly functionalised F-BODIPYs without need for the corresponding aryl moiety to be available in borylated form

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Published Version: Craig D. Smith and Alison Thompson. 2021. The Suzuki–Miyaura reaction of BPin-substituted F-BODIPYs with aryl halides. Canadian Journal of Chemistry. 99(3): 287-294. https://doi.org/10.1139/cjc-2020-0300

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