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dc.contributor.authorTien, Chieh Hung
dc.date.accessioned2018-04-04T18:27:21Z
dc.date.available2018-04-04T18:27:21Z
dc.identifier.urihttp://hdl.handle.net/10222/73820
dc.description.abstractCatalysis plays a key role in the industrial production of many refined goods. Catalysts derived from precious metals are especially prevalent in industry due to their high stereoselectivity, and low loadings. To alleviate the reliance on precious metals, catalysts derived from cheaper, more abundant main group elements have attracted much attention in recent years. 1,3,2-Diazaphospholenes developed by Gudat, Kinjo, and our group have shown great potential in the reduction of various unsaturated carbons including imines, carbonyls, olefins, etc. In an effort to uncover catalytic activity in more elaborate heterocycles, I have developed a new class of hydroboration catalysts, namely 1,2,4,3-triazaphospholenes. The synthesis towards 1,2,4,3-triazaphospholenes and their reactivity in the racemic and non-racemic hydroboration of imines and carbonyls are disclosed herein.en_US
dc.language.isoenen_US
dc.subjectHydroborationen_US
dc.subjectReductionen_US
dc.subjectMain Group Chemistryen_US
dc.subjectTriazaphospholeneen_US
dc.subjectTAPen_US
dc.subjectBifunctional Catalysten_US
dc.subjectCatalysisen_US
dc.subjectMain Group Catalysisen_US
dc.subjectHeterocycleen_US
dc.subjectOrganic Chemistryen_US
dc.subjectReductive Catalysisen_US
dc.titleSynthesis and Catalytic Activity of 1,2,4,3-Triazaphospholenesen_US
dc.date.defence2018-03-08
dc.contributor.departmentDepartment of Chemistryen_US
dc.contributor.degreeMaster of Scienceen_US
dc.contributor.external-examinern/aen_US
dc.contributor.graduate-coordinatorProf. Mark Stradiottoen_US
dc.contributor.thesis-readerProf. Erin R. Johnsonen_US
dc.contributor.thesis-readerProf. Mark Stradiottoen_US
dc.contributor.thesis-supervisorProf. Alexander W. H. Speeden_US
dc.contributor.ethics-approvalNot Applicableen_US
dc.contributor.manuscriptsYesen_US
dc.contributor.copyright-releaseYesen_US
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