| dc.contributor.author | Smithen, Deborah A. | |
| dc.contributor.author | Baker, Alexander E. G. | |
| dc.contributor.author | Offman, Matthew | |
| dc.contributor.author | Crawford, Sarah M. | |
| dc.contributor.author | Cameron, T. Stanley | |
| dc.contributor.author | Thompson, Alison | |
| dc.date.accessioned | 2018-11-01T17:34:37Z | |
| dc.date.available | 2018-11-01T17:34:37Z | |
| dc.date.issued | 2012 | |
| dc.identifier.citation | Smithen, D. A., Baker, A. E., Offman, M., Crawford, S. M., Cameron, T. S., & Thompson, A. (2012). Use of F-BODIPYs as a protection strategy for dipyrrins: optimization of BF2 removal. The Journal of organic chemistry, 77(7), 3439-3453. DOI: 10.1021/jo3002003 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10222/74926 | |
| dc.description | - Post-print
- Must link to publisher version | en_US |
| dc.description.abstract | We recently reported the first general method for the deprotection of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes (F-BODIPYs) involving a microwave-assisted procedure for the removal of the BF2 moiety, and liberation of the corresponding free-base dipyrrin. Further optimization of the reaction has resulted in a more convenient and accessible protocol. The availability of this new methodology enables BF2-complexation to be used as a dipyrrin protection strategy. Herein lies a detailed examination of the deprotection reaction, with a view to optimization and gaining mechanistic insight, and its application in facilitating a multistep synthesis of pyrrolyldipyrrins. | en_US |
| dc.publisher | Journal of Organic Chemistry | en_US |
| dc.title | Use of F-BODIPYs as a protection strategy for dipyrrins: optimization of BF2 removal. | en_US |
| dc.type | Article | en_US |
