| dc.contributor.author | Thompson, Alison | en_US |
| dc.contributor.author | Garabatos-Perera, Jose R. | en_US |
| dc.contributor.author | Gillis, H. Martin | en_US |
| dc.date.accessioned | 2013-08-12T17:55:03Z | |
| dc.date.available | 2013-08-12T17:55:03Z | |
| dc.date.issued | 2008-07 | en_US |
| dc.identifier.citation | Thompson, Alison, Jose R. Garabatos-Perera, and H. Martin Gillis. 2008. "Asymmetric oxidation of 2-(arylsulfenyl)pyrroles." Canadian Journal of Chemistry-Revue Canadienne De Chimie 86(7): 676-681. | en_US |
| dc.identifier.issn | 0008-4042 | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1139/V08-054 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10222/30742 | |
| dc.description.abstract | The asymmetric oxidation of prochiral 2-(arylsulfenyl)pyrroles has been investigated. A marked
electronic effect within the substrate significantly influenced the degree of enantioselectivity
obtained, with very high enantio selectivity being obtained for
5-(nitrobenzensulfenyl)pyrrole-2-carboxaldehydes using Ti(i-PrO)(4)/(+)-(R,R)-DET/H(2)O/CHP. This
result bodes well for optimizing the asymmetric oxidation of other diaryl sulfides, substrates that
have previously given only low enantiomeric excesses. | en_US |
| dc.relation.ispartof | Canadian Journal of Chemistry-Revue Canadienne De Chimie | en_US |
| dc.title | Asymmetric oxidation of 2-(arylsulfenyl)pyrroles | en_US |
| dc.type | article | en_US |
| dc.identifier.volume | 86 | en_US |
| dc.identifier.issue | 7 | en_US |
| dc.identifier.startpage | 676 | en_US |
