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Synthesis and characterisation of the unsubstituted dipyrrin and 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene: improved synthesis and functionalisation of the simplest BODIPY framework
(2013)
An improved and scalable synthesis of the unsubstituted
4,4-difluoro-4-bora-3a,4a-diaza-s-indacene framework facilitates access to the previously unreported
parent dipyrrin HCl salt, as well as 4,4-dichloro-4-bora-3a,4a- ...
Conversion of F-BODIPYs to Cl-BODIPYs: Enhancing the Reactivity of F-BODIPYs
(2013-01)
A new method for the synthesis of Cl-BODIPYs from F-BODIPYs is reported, merely requiring
treatment of the F-BODIPY with boron trichloride. Cl-BODIPYs are exploited as synthetic
intermediates generated in situ for the ...