| dc.contributor.author | Campbell, J.W. | |
| dc.contributor.author | Tung, M.T. | |
| dc.contributor.author | Robertson, K.N. | |
| dc.contributor.author | Beharry, A.A. | |
| dc.contributor.author | Thompson, A. | |
| dc.date.accessioned | 2023-07-17T22:26:42Z | |
| dc.date.available | 2023-07-17T22:26:42Z | |
| dc.date.issued | 2023-07-13 | |
| dc.identifier.citation | BODIPYs with Chalcogenophenes at Boron: Synthesis and Properties Jacob W. Campbell, Matthew T. Tung, Katherine N. Robertson, Andrew A. Beharry, and Alison Thompson The Journal of Organic Chemistry Article ASAP DOI: 10.1021/acs.joc.3c00708 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10222/82699 | |
| dc.description.abstract | Reported herein are the synthesis and characterization of BODIPYs bearing heterocycles at boron. To synthesize this series, various chalcogenophenes (furan, thiophene, selenophene, and tellurophene) were lithiated and then used as nucleophiles to attack the boron center of a parent F-BODIPY. Compounds in the series were compared with respect to their photophysical and structural properties, and trends were discussed. By virtue of the “heavy atom effect”, as the mass of the heterocycle appended to the BODIPY core increases, compounds exhibit a higher singlet oxygen quantum yield. The BODIPY with tellurophene at boron exhibits the highest quantum yield (ΦΔ = 0.68) in the series and reduced emission (Φf = 0.01). | en_US |
| dc.publisher | J. Org. Chem. | en_US |
| dc.relation.ispartof | BODIPYs with Chalcogenophenes at Boron: Synthesis and Properties. | en_US |
| dc.title | BODIPYs with Chalcogenophenes at Boron: Synthesis and Properties. Postprint | en_US |
| dc.type | Article | en_US |
