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dc.contributor.authorBriand, Glen Gerard.en_US
dc.date.accessioned2014-10-21T12:33:29Z
dc.date.available1999
dc.date.issued1999en_US
dc.identifier.otherAAINQ49247en_US
dc.identifier.urihttp://hdl.handle.net/10222/55625
dc.descriptionThe serendipitous discovery and pharmaceutical use of bismuth compounds, along with fundamental interests, has prompted a century of chemical and clinical studies of bismuth complexes and preparations. The characteristic hydrolytic instability and polymeric nature of these materials has deterred comprehensive chemical studies. As a result, the chemistry of bismuth, as for many elements of the periodic table, remains in its infancy. This work establishes the utility of bifunctional ligands: as a method to overcoming these obstacles, and represents significant developments in the thiolate and carboxylate chemistry of bismuth, the latter of which encompasses pharmaceutical implications. The synthetic guidelines outlined are likely to be generally applicable to other metals and various bifunctional ligand combinations.en_US
dc.descriptionThesis (Ph.D.)--Dalhousie University (Canada), 1999.en_US
dc.languageengen_US
dc.publisherDalhousie Universityen_US
dc.publisheren_US
dc.subjectChemistry, Inorganic.en_US
dc.subjectChemistry, Pharmaceutical.en_US
dc.titleBifunctional ligands in discerning and developing the fundamental and medicinal chemistry of bismuth(III).en_US
dc.typetexten_US
dc.contributor.degreePh.D.en_US
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