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Synthesis and characterisation of the unsubstituted dipyrrin and 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene: improved synthesis and functionalisation of the simplest BODIPY framework
(2013)
An improved and scalable synthesis of the unsubstituted
4,4-difluoro-4-bora-3a,4a-diaza-s-indacene framework facilitates access to the previously unreported
parent dipyrrin HCl salt, as well as 4,4-dichloro-4-bora-3a,4a- ...
Cl-BODIPYs: a BODIPY class enabling facile beta-substitution
(2012-01)
Cl-BODIPYs, synthesized in high yields from dipyrrins under air- and moisture-free conditions,
are extremely facile to substitution at boron compared to their corresponding F-BODIPYs, opening up
a new route to BODIPYs ...
Synthesis of natural products containing the pyrrolic ring
(2010)
This review provides an overview of the synthetic chemistry that has been utilised to prepare
natural products containing a pyrrolic ring.
Conversion of F-BODIPYs to Cl-BODIPYs: Enhancing the Reactivity of F-BODIPYs
(2013-01)
A new method for the synthesis of Cl-BODIPYs from F-BODIPYs is reported, merely requiring
treatment of the F-BODIPY with boron trichloride. Cl-BODIPYs are exploited as synthetic
intermediates generated in situ for the ...
Chloride anion transport and copper-mediated DNA cleavage by C-ring functionalized prodigiosenes
(2007)
A new class of prodigiosenes with stability-enhancing functionalities appended to the C-ring
were found to transport chloride anions through liposomal membranes, as well as to induce
copper-mediated DNA cleavage.
Investigations into the nucleophilic meso-substitution of F-BODIPYs and improvements to the synthesis of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene.
(2011)
A series of three F-BODIPYs, with varying levels of steric crowding about the meso-position were
selected to investigate nucleophilic meso-substitution of F-BODIPYs. The synthesis of one of these
F-BODIPYs, 4,4-difluor ...
The first series of alkali dipyrrinato complexes
(2010-08)
The first series of alkali dipyrrinato complexes is reported, encompassing lithium, sodium, and
potassium salts of meso-unsubstituted and meso-aryl-substituted derivatives. By varying the
substituents at the meso position, ...
Thionation Reactions of 2-Pyrrole Carboxylates
(RSC, 2016)
Prodigiosenes Conjugated to Tamoxifen and Estradiol
(Royal Society of Chemistry, 2017)