Browsing Chemistry by Title
Now showing items 21-40 of 234
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A calorimetric investigation of the low-temperature phase transition in sodium hydroxide-d.
(1986)The heat capacity of NaOD from 20 to 350 K is reported. An anomaly centered at 153.2 ± 0.1 K (?H = 131.1 ± 0.7 J/mol, ?S = 0.864 ± 0.005 J/K.mol) corresponds to the onset of a low-temp. antiferroelec. phase. This ... -
Calorimetric, Spectroscopic, and Structural Studies of Anhydrous Zinc Bromide
(1984)No abstract available. -
Celebrating the 200th anniversary of Dalhousie University in Halifax, Nova Scotia, Canada.
(Canadian Journal of Chemistry, 2018) -
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Chemical Constituents from Stem Bark and Roots of Clausena anisata
(2012-11)Phytochemical investigations on the stem bark and roots of the tropical shrub Clausena anisata led to the isolation and characterization three carbazole alkaloids: girinimbine, murrayamine-A and ekeberginine; two peptide ... -
Chiral molecules containing the pyrrole framework
(2010)This review summarizes strategies by which chiral pyrroles, both simple and complex, have been prepared: strategies include formation of the pyrrolic ring using starting materials appended with chirality, as well as the ... -
Chloride anion transport and copper-mediated DNA cleavage by C-ring functionalized prodigiosenes
(2007)A new class of prodigiosenes with stability-enhancing functionalities appended to the C-ring were found to transport chloride anions through liposomal membranes, as well as to induce copper-mediated DNA cleavage. -
cis-3,5-Cyclohexadiene-1,2-diol derivatives: facial selectivity in their Diels-Alder reactions with ethylenic, acetylenic and azo dienophiles
(2006)The Diels - Alder reactions of maleimide with the acetonide derivative (6a) of cis-3,5-cyclohexadiene-1,2-diol (1a) in various solvents showed facial selectivities ranging from 1 : 1 to 1 : 9. The same derivative 6a reacted ... -
Cl-BODIPYs: a BODIPY class enabling facile beta-substitution
(2012-01)Cl-BODIPYs, synthesized in high yields from dipyrrins under air- and moisture-free conditions, are extremely facile to substitution at boron compared to their corresponding F-BODIPYs, opening up a new route to BODIPYs ... -
Classifying donor strengths of dipyrrinato/aza-dipyrrinato ligands
(2019)A parameter is reported by which to use 13C NMR chemical shifts to measure and predict the donor capabilities of N^N dipyrrinato and aza-dipyrrinato ligands chelating in L^X fashion. The results enable the rationalisation ... -
A Combinatorial Investigation of Fe-Si-Zn Thin Film Negative Electrodes for Li-ion 1 Batteries (Preprint)
(IOP Publishing, 2014-12-04)Thin-film Fe-Si-Zn libraries were investigated as negative electrode materials for Li-ion batteries using combinatorial and high-throughput techniques. X-ray diffraction and electron microprobe measurements were used to ... -
A Combinatorial Investigation of Fe-Si-Zn Thin Film Negative Electrodes for Li-ion 2 Batteries (Preprint)
(IOP Publishing, 2014-11-07)Sodium-ion batteries have the potential to be a low cost, sustainable replacement for lithium-ion batteries in large scale energy storage. The lack of practical negative electrode materials limit the development of Na-ion ... -
Combinatorial Investigations of Ni-Si Negative Electrode Materials for Li-Ion Batteries
(IOPscience, 2015-06-30)Sputtered thin films in the Ni-Si system (0 ≤ x ≤ 0.65 in NixSi1-x) were studied for use as anode materials in Li-ion cells. All compositions were found to be amorphous. The Ni in Ni-Si films was found to suppress the ... -
Combinatorial Study of the Si-Sn-O System as Negative Electrode Materials in Li-Ion Cells
(The Electrochemical Society, 2015-11-17)SixSnyO1-x-y films with 0.45 < x < 0.80, 0.05 < y < 0.35, and 0.05 < (1-x-y) < 0.40 have been prepared using a magnetron sputtering method. All compositions had an amorphous structure and good capacity retention. Reversible ... -
Composite and Low-Cost Approaches for Molecular Crystal Structure Prediction
(American Chemical Society, 2018) -
A computational exploration of the crystal energy and charge carrier mobility landscapes of the chiral [6]helicene molecule
(Royal Society of Chemistry, 2018) -
Computational Modeling of Piezochromism in Molecular Crystals
(American Institute of Physics, 2020-06-15) -
Conversion of F-BODIPYs to Cl-BODIPYs: Enhancing the Reactivity of F-BODIPYs
(2013-01)A new method for the synthesis of Cl-BODIPYs from F-BODIPYs is reported, merely requiring treatment of the F-BODIPY with boron trichloride. Cl-BODIPYs are exploited as synthetic intermediates generated in situ for the ... -
Correct charge transfer in CT complexes from the Becke’05 density functional
(American Institute of Physics, 2018)