Browsing Faculty of Graduate Studies Online Theses by Subject "Allenyl Vinyl Ketones"
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Development of the Interrupted Nazarov Cyclization of Allenyl Vinyl Ketones, with Application to the Total Synthesis of the Cyclooctane Natural Product Roseadione
(2011-07-06)The development of the interrupted Nazarov cyclization of allenyl vinyl ketones is presented. The intermediate oxyallyl cation, derived from an allenyl vinyl ketone, may be trapped efficiently by a divergent array of ... -
Stereochemical Aspects in the Interrupted Nazarov Reaction of Allenyl Vinyl Ketones: A Computational Study
(2014-07-24)Transition state models are often invoked to explain stereochemical outcomes in chemical reactions. The relevance of these models to correctly predict these outcomes can be further validated by studying reactions where ...