Browsing Obrovac, Mark N. by Submit Date
Now showing items 21-40 of 45
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Inorganic Compounds as Binders for Si-Alloy Anodes
The inorganic compounds, lithium polysilicate (Li2Si5O11), sodium polyphosphate ((NaPO3)n), and lithium phosphate monobasic (H2LiPO4) were investigated as the sole binders in Si-alloy and graphite electrodes for Li cells. ... -
Isothermal Calorimetry Evaluation of Metallurgical Silicon as a Negative Electrode Material for Li-Ion Batteries
The structural evolution of Si during lithiation and delithiation is uniquely dependent on the cycling conditions and can show either reversible or path dependent behavior. In this paper, metallurgical Si (large crystalline ... -
Si85Fe15Ox Alloy Anode Materials with High Thermal Stability for Lithium Ion Batteries
The synthesis, microstructure and electrochemical properties of ball milled Si85Fe15Ox alloys with different oxygen contents are investigated. These materials combine the features of Si-M alloys (low irreversible capacity) ... -
Preparation of Low Surface Area Si-Alloy Anodes for Li-Ion Cells by Ball Milling
A new and simple 2-step milling technique is utilized to produce Si–Ti–N alloys with significantly reduced surface area compared to conventional ball milling, while still attaining a full amorphous active Si phase. Surface ... -
Sintered polymeric binders for Li-ion battery alloy anodes
The cycling performance in lithium half cells of Si alloy electrodes with polyvinylidene fluoride or polyimide binders were evaluated after the electrodes were cured at temperatures below and above the binder carbonization ... -
Li Insertion in Ball Milled Si-Mn Alloys
Si1-xMnx (0 ≤ x ≤0.5, x=0.05)alloyswereprepared by ball milling and studied as negative electrode materials in Li cells. These alloys were found to be unique amongtransition metals. When x ≤ 0.35, the alloys are essentially ... -
An Investigation of the Fe-Mn-Si System for Li-Ion Battery Negative Electrodes
Fe-Mn-Si alloys prepared by ball milling were investigated as negative electrodes for Li-ion batteries. X-ray diffraction and room temperature 57Fe Mössbauer measurements were used to characterize alloy structure, which ... -
Stabilizing NaCrO2 by Sodium Site Doping with Calcium
Layered cathode materials based on abundant, low cost raw materials have garnered interest in recent years. O3-type NaCrO2 is a promising cathode material as it offers decent energy density and is easy to synthesize. In ... -
Quantitative Determination of Carbon Dioxide Content in Organic Electrolytes by Infrared Spectroscopy
CO2 has been shown to be an effective additive to improve the cycling characteristics of silicon negative electrodes for Li-ion batteries. However, a quantitative technique for measuring the CO2 content in electrolyte is ... -
Spherically Smooth Cathode Particles by Mechanofusion Processing
Surface modification has been shown to be useful for improving the cycling performance of cathode materials. Typically hetero-compositional coatings are applied on cathode particle surfaces using methods, such as aqueous ... -
Polyaniline Electrode Activation in Li Cells
Polyaniline (PANi) can be used as an electroactive organic cathode material in Li-cells with multiple redox states. The theoretical specific capacity of the emeraldine base (PEB) is 150 mAh g−1. In this study, we show how ... -
Engineered Particle Synthesis by Dry Particle Microgranulation
Highlights * A method of making monodisperse engineered ∼10-μm particles is introduced * Core-shell, spherical, and tetrahedral particles demonstrated at ∼100% yield * Spherical layered oxides for Li-ion batteries ... -
Electrochemistry and Thermal Behavior of SiOx Made by Reactive Gas Milling
SiOx with various oxygen contents were synthesized from Si powder by a simple room-temperature ball milling method by controlling the air exposure time during milling. The resulting SiOx consists of nano and amorphous Si ... -
Synthesis, Lithium Insertion and Thermal Stability of Si–Mo Alloys
Li insertion was investigated in SixMo100−x (90 ≥ x ≥ 70, Δx = 10) alloys prepared by mechanical ball milling. X-ray diffraction (XRD) and quantitative phase analysis were used to analyze phase compositions of these Si–Mo ... -
A Combinatorial Investigation of Fe-Si-Zn Thin Film Negative Electrodes for Li-ion 1 Batteries (Preprint)
Thin-film Fe-Si-Zn libraries were investigated as negative electrode materials for Li-ion batteries using combinatorial and high-throughput techniques. X-ray diffraction and electron microprobe measurements were used to ... -
A Combinatorial Investigation of Fe-Si-Zn Thin Film Negative Electrodes for Li-ion 2 Batteries (Preprint)
Sodium-ion batteries have the potential to be a low cost, sustainable replacement for lithium-ion batteries in large scale energy storage. The lack of practical negative electrode materials limit the development of Na-ion ... -
Mixed Transition Metal Titanate and Vanadate Negative Electrode Materials for Na-Ion Batteries (Preprint)
Sodium-ion batteries have the potential to be a low cost, sustainable replacement for lithium-ion batteries in large scale energy storage. The lack of practical negative electrode materials limit the development of Na-ion ... -
The Reversible Magnesiation of Pb (Preprint)
Sputtered Pb films have been found to reversibly alloy electrochemically with magnesium in Grignard based electrolytes. The voltage curve shows a single plateau at about 125 mV vs. Mg, corresponding to the formation of ... -
Mössbauer and Electrochemical Investigations of Carbon-Rich Fe1-xCx Films (Preprint)
A thin film binary library of carbon-rich Fe1-xCx (0.47 ≤ x ≤ 0.97) alloys was prepared by combinatorial sputtering of carbon and iron. The sputtered library was characterized by X-ray diffraction and room temperature 57Fe ... -
Investigation of the NaNixMn1-xO2 (0 ≤ x ≤ 1) System for Na-ion Battery Cathode Materials (Preprint)
Layered NaNixMn1-xO2 (0 ≤ x ≤ 1) oxides were prepared via solid state reactions. Different reaction conditions were required to obtain phase pure samples, depending on the value of x. The 0 ≤ x ≤ 0.1 compositions were ...